Journal of Engineering Geology

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One of the most important issues in the design and implementation of engineering structures is to evaluate and investigate their durability against processes of consecutive wear, wet and dry. The durability of rock is resistance against chemical and physical weathering, the shape, size and status of the initial appearance in a long time and environmental conditions prevailing in the rock, hence it is important to evaluate the durability of rock. Since the device of standard durability (Franklin & Chandra, 1972) designed to evaluate and investigate durability of soft and argillites rocks. So, appears to be essential to design a durability device, which can evaluate hard rocks. For this purpose, Researchers of the Department of Geological Engineering, Tarbiat Modares University, durability device as "large-scale durability device " was designed and built which the length and diameter of the device, is 6 and 4.3 times standard durability device, respectively, and needs 10 samples with weight of 400 to 600 g. In order to investigation the applicability of this device for hard rocks durability, we selected 17 building rocks samples of the igneous, sedimentary, metamorphic and pyroclastic rocks. Then their mineralogical, physical and mechanical properties were investigated. More, experiments of standard and large-scale durability up to 15 cycles were performed and data obtained were analyzed. The results show that, the large-scale durability device than standard durability, have more applicability for evaluating the durability of hard rocks.

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Introduction
Loess soil is one of the problematic soils that should be improved its geotechnical properties before the project is implemented. Lack of attention to this issue has caused in many problems for civil projects in Golestan province. This has been more evident in some of the rural areas built on this type of soil. Moreover there are many reports regarding different geological hazard such as subsidence, divergence, erosion and landslide in Golestan loess soil. Among the different types of loess soils found in Golestan province, silty loess should be given more attention due to their large extent and being the bed soil of many villages, and many reports of its hazards.
One of the methods for improving soil mechanical behavior and its geotechnical properties is to use additives to reduce geological hazards. Due to the fine-grained structure of loess soils, the application of nanoparticles is more efficient and could result in solving many of the related problems. Nanotechnology is new scientific field which affects many aspects of engineering and in recent years, many efforts have been made to use this new technology in various geotechnical branches.
So far, research has been carried out on the improvement of various soil types with additives such as cement, bitumen, ash, lime and various types of nanoparticles. Nowadays, the use of nanoparticle additives due to reduction of environmental pollution than other additives has a wider application in improving the physical and chemical properties of problematic soils.
In the present study, the effect of nano-kaolinite on strength properties including uniaxial compressive strength, elasticity modulus, cohesion, and internal friction angle of silty Loess in Kalaleh city of Golestan province have been investigated.
Material and methods
In order to carry out the present research, sample of the silty loess soil from Kaleh city of Golestan province was collected and prepared. Then, 0.5, 1, 1.5, 2, 3 and 4 weight percent of nano-kaolinite were added to soil samples. The soil samples were prepared in a natural state (without additives) and with the additive for uniaxial compressive strength and direct shear tests. Strength properties of soil specimens including uniaxial compressive strength, elastic modulus (based on uniaxial compressive strength test), cohesion and internal friction angle (based on direct shear testing) were determined for native soil and its mixture with different percentage of nano-kaolinite. The data were analyzed and the effect of nano-kaolinite on the strength properties of the silty loess soil sample was investigated.
Results and discussion
Uniaxial compressive strength and modulus of elasticity have been increased with increasing amount of nano-kaolinite, and after 2% nano-kaolinite, increase in nano-kaolinite did not have any significant effect on uniaxial compressive strength and modulus of elasticity. The uniaxial compressive strength and the modulus of soil elasticity in the natural state (without nano-kaolinite) are 1.12 and 15.89 kg/cm² respectively, and when 2% of the nano-kaolinite is added to the soil, the values ​​of these properties are maximal and reached to 1.19 and 18.10 kg/cm², respectively.
For native soil (without nano-kaolinite), the cohesion value is equal to 0.09 kg/cm², and with increasing nano-kaolinite from 0.5 to 2%, the cohesion shows an incremental trend and reached to 0.16 kg/cm². With increasing the additive percent from 2 to 4% the amount of cohesion were constant and equal to 0.16 kg/cm². The increasing of cohesion can be attributed to the fact that nanoparticles enhanced water absorption of soil particles which caused in better cohesion and also they affected chemical actions and surface electrical charge of soil particles.
Conclusion
The results of the uniaxial compressive strength tests show that adding up to 2 weight percent Nano-kaolinite to the dry soil increases the uniaxial compressive strength and modulus of elasticity of silty loess soil in the Golestan province, which can be due to proper locking between the nanoparticles and soil particles and increased cohesion.
The results of direct shear tests showed that adding up to 2% nano-kaolinite to dry soil increased the cohesion of the soil and consequently increased the shear strength of the soil.
On the other hand, adding the different amount of nano-kaolinite has not changed much in the internal friction angle of the silty loess soil in the Golestan province.
 
 

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Groundwater salinization in semiarid regions is a limiting factor of use with strategic importance. In this study, the sources of salinity, chemistry, and quality of groundwater in Robat (Khorramabad plain, Iran) were identified through the geochemical methods. Using data analysis, the concentration of cations and anions were recognized with the order of Ca²⁺>Na⁺ >Mg²⁺>K⁺ and HCO₃^-> Cl^-> SO₄²⁺> NO₃^-> F^-, respectively. The high concentration of Na⁺, Cl^-, and EC in some places is attributed to the gypsum and salty formations. In the study area, the salinization processes are identified by natural and artificial activities. The salinization mechanisms are identified by the natural dissolution of gypsum and salt from Gachsaran formation and man-made sources including boreholes drilled through Gachsaran Formation, salt mining, and agricultural activity. Also, the high concentration of nitrate is related to agricultural fertilizers and karstification effects. It is seen that the atmospheric NO₃^-. HCO₃^-, Ca²⁺, and Mg²⁺ concentration exceeded the standard limit in a few samples probably due to the calcareous formation. Besides, hydrochemical facies of the groundwater are Ca- HCO₃ and Na-K-HCO₃. Due to the presence of calcareous and salt bearing formations, 46%, 26%, and 20% of all samples show a higher concentration of Ca²⁺, Na+, and Mg²⁺, respectively, which exceed the permissible limits. Sulfate and fluoride concentrations are less than the permissible limits. However, due to the presence of calcareous formation, salt bearing formation, and use of agricultural fertilizers, 100%, 26%, and 20% of all samples show a higher concentration of HCO₃^-, Cl^-, and NO₃^- than the permissible limits.