Journal of Engineering Geology

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Groundwater salinization in semiarid regions is a limiting factor of use with strategic importance. In this study, the sources of salinity, chemistry, and quality of groundwater in Robat (Khorramabad plain, Iran) were identified through the geochemical methods. Using data analysis, the concentration of cations and anions were recognized with the order of Ca²⁺>Na⁺ >Mg²⁺>K⁺ and HCO₃^-> Cl^-> SO₄²⁺> NO₃^-> F^-, respectively. The high concentration of Na⁺, Cl^-, and EC in some places is attributed to the gypsum and salty formations. In the study area, the salinization processes are identified by natural and artificial activities. The salinization mechanisms are identified by the natural dissolution of gypsum and salt from Gachsaran formation and man-made sources including boreholes drilled through Gachsaran Formation, salt mining, and agricultural activity. Also, the high concentration of nitrate is related to agricultural fertilizers and karstification effects. It is seen that the atmospheric NO₃^-. HCO₃^-, Ca²⁺, and Mg²⁺ concentration exceeded the standard limit in a few samples probably due to the calcareous formation. Besides, hydrochemical facies of the groundwater are Ca- HCO₃ and Na-K-HCO₃. Due to the presence of calcareous and salt bearing formations, 46%, 26%, and 20% of all samples show a higher concentration of Ca²⁺, Na+, and Mg²⁺, respectively, which exceed the permissible limits. Sulfate and fluoride concentrations are less than the permissible limits. However, due to the presence of calcareous formation, salt bearing formation, and use of agricultural fertilizers, 100%, 26%, and 20% of all samples show a higher concentration of HCO₃^-, Cl^-, and NO₃^- than the permissible limits.